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81.
Domy C. Adriano Hyo T. Chon Sally L. Brown Rosanna Ginocchio 《中国地球化学学报》2006,25(B08):45-46
Metals, including heavy metals and metalloids, are a common group of environmental contaminants. Their sources in the environment are geogenic or anthropogenic. The growing trend in global industrialization ensures that more metals could be dispersed even in pristine ecosystems. To fuel industrialization, more metal ore mines have to be discovered and explored. These explorations often result in landscape disturbance, soil degradation and environmental contamination by unwanted mining constituents. Mine tailings brought up to the ground surface often serve as the main source of contaminants when these pyrite-rich materials oxidize. The oxidation of mine tailings results in proton generation, coupled with the dissolution of metals and other cations Unwanted anionic constituents are also produced. The so-called "acid mine drainage" may affect the productivity of farmlands and stability of receiving streams and other bodies of water-acidifying the waters and enriching the ecosystem with metals, i.e., high total dissolved solids. The acidified overburden materials become inhospitable to plant and microbial life as they are typically low in organic matter content and infertile. This exposes the landscape to runoff and erosion. 相似文献
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83.
Vincent Artus Louis J. Durlofsky Jérôme Onwunalu Khalid Aziz 《Computational Geosciences》2006,10(4):389-404
The determination of the optimal type and placement of a nonconventional well in a heterogeneous reservoir represents a challenging optimization problem. This determination is significantly more complicated if uncertainty in the reservoir geology is included in the optimization. In this study, a genetic algorithm is applied to optimize the deployment of nonconventional wells. Geological uncertainty is accounted for by optimizing over multiple reservoir models (realizations) subject to a prescribed risk attitude. To reduce the excessive computational requirements of the base method, a new statistical proxy (which provides fast estimates of the objective function) based on cluster analysis is introduced into the optimization process. This proxy provides an estimate of the cumulative distribution function (CDF) of the scenario performance, which enables the quantification of proxy uncertainty. Knowledge of the proxy-based performance estimate in conjunction with the proxy CDF enables the systematic selection of the most appropriate scenarios for full simulation. Application of the overall method for the optimization of monobore and dual-lateral well placement demonstrates the performance of the hybrid optimization procedure. Specifically, it is shown that by simulating only 10% or 20% of the scenarios (as determined by application of the proxy), optimization results very close to those achieved by simulating all cases are obtained. 相似文献
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85.
Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230
Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream (pH 2.98-3.40), 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization. 相似文献
86.
Structural changes during dehydration and subsequent decomposition in thaumasite Ca3Si(SO4)(CO3)(OH)6·12 H2O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P63 space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass. 相似文献
87.
Connectivity is an important measure for assessing flow transport in rock, especially through fractures. In this paper, rock
fracture systems are modelled by a discrete fracture model simulated by a marked point process. A connectivity index is then
introduced to quantify the connectivity between any two points in space. Monte Carlo simulation is used to evaluate the connectivity
index for stationary cases and relationships between the connectivity index and the parameters of the discrete fracture model
are analysed. The average number of intersections per fracture, Xf, and the fracture intensity, P12 (P32), are calculated and the relationships between these parameters and the connectivity index are investigated, concluding that
Xf is the more suitable parameter for the classification of rock mass flow properties. The relationships between the connectivity
index and the percolation state of the fractured medium are also discussed. An edge correction is briefly discussed and a
practical example is used to demonstrate the method of computing the connectivity index. 相似文献
88.
89.
1 Introduction Urban agglomeration is a system of cities, supporting by the modern transportation and information network in the system, these cities, with different characteristics, types, sizes and hierarchies, interact with each other, and one or two … 相似文献
90.
全球及区域模式中陆面过程的地表植被覆盖分类方法 总被引:1,自引:0,他引:1
全球和区域尺度上陆面生态系统与气候密切相关。全球和区域模式的发展对于我们认识气候与陆地生态的变化起到重要作用。在这些模型中,植被覆盖是影响大气-植被间热量、水分和CO2等交换的重要陆面参数。在分析了陆地植被覆盖分类原理基础上,介绍了目前全球不同植被覆盖分类方案,包括基于地基观测的植被分布、基于生物气候特征的分类方案(如:Holdridge的方案);特别近年来陆面过程试验表明,各种遥感数据源(如:NOAA—AVHRR,EOS—MODIS,Landsat—TM)等为我们提供了有利的工具来监测全球植被动态,完善植被分类,并且采用高时空分辨率的全球土地覆盖状况特征,在不同时空尺度揭示植被-大气相互作用。本文分析了代表性的3种基于卫星遥感技术的陆面植被分类方案,分别是BATS(18类)、SIB(9类)、SIB2(12类)和BIOME—BGC(31类)陆地模式的植被覆盖分类方案.最后分析了目前可用于全球植被覆盖分类的新的遥感数据库。 相似文献